the part of a shoe or stocking that covers the arch of the foot
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Instep \In"step\, n. [Formerly also {instop}, {instup}.] 1. The arched middle portion of the human foot next in front of the ankle joint.
2. The part of a shoe, boot, or stocking covering the instep[1]. [PJC]
3. That part of the hind leg of the horse and allied animals, between the hock, or ham, and the pastern joint.
He pioneered the now standard "around-the-world" move, kicking the bag about chest-high with his instep, or the inside or outside of his ankle, then circling the flying bag with his foot a few times before catching it on his shoe.