cycloaddition [
,saikləuə'diʃən]
[化] 环加成
- This paper focuses on the cycloaddition reactions on solid phase supports and their applications in organic synthesis and mechanism research.
本文介绍了在固相载体上进行的环加成反应,及其在有机合成及反应机理研究中的应用。 - The system of[4+3] cycloaddition and its application in organic synthesis are reviewed. A brief discussion about the future research is also given.
本方对[+]加成反应体系以最近在合成中的应用进行了综述,并对进一步研究的方向进行了讨论。 - Polyethylene glycol supported( diacetoxy) iodobenzene as a soluble polymer reagent can smoothly oxidize aldehyde phenylhydrazones to generated nitrilimines in situ, which can be trapped by methyl acrylate to carry out1,3 dipolar cycl
聚乙二醇支持的二醋酸碘苯作为可溶性聚合物试剂可在温和的反应条件下将醛的苯基腙氧化成为腈亚胺中间体,该中间体进而可与丙烯酸甲酯发生1,3偶极环加成反应,以良好的产率和完全的区域选择性生成吡唑啉衍生物。
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