反应能垒 [
fǎn yìng néng lěi]
[物化] reaction energy barrier
- 结果表明:对单羰基体系,羰基碳的亲电性对反应能垒有重要的影响;
It is demonstrated that: (1) for the monocarbonyl system, the electrophilicity of the carbonyl carbon affects significantly the reactive energy barrier; - 根据各个反应通道的能垒数和能垒的高度,确定了最可几的反应通道及最可几的产物碎片的来源。
Judged by the number of transition states and the height of energy barriers, the most impossible reaction pathway and the most possible fragments are inferred.